Technical Centre — Selection & Regeneration

Selection, specification and regeneration

How to choose a grade, what the numbers on a data sheet actually mean, and how to regenerate a bed without cooking the sieve. Written for engineers specifying or operating a vessel, and for buyers who have to justify the choice.

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Choosing a grade

If the duty isChooseBecause
Drying unsaturated hydrocarbons, cracked gas, ethylene, propylene, LPG, refrigerants3AThe 3 Å opening takes water and excludes the molecule you are drying
General gas and liquid drying, natural gas, sealed packaging4ALarger opening and higher capacity where co-adsorption does not matter
Separating normal from iso-paraffins; PSA oxygen or hydrogen purification5A5 Å admits normal paraffins and excludes the branched ones
Air separation feed clean-up: water and CO2 together13X / 13X APG10 Å takes both in one bed; APG is made for the duty
VPSA or PSA oxygen, medical oxygen concentratorsLi-LSXHighest nitrogen capacity per unit bed volume
PSA nitrogen generationCarbon molecular sieveSeparates by rate, so short cycles produce nitrogen without a cryogenic plant
Moisture inside a sealed insulating glass unit3A4A would co-adsorb nitrogen from the sealed cavity and deflect the glass

Reading a data sheet

NumberWhat it tells youWhat it does not tell you
Static water adsorptionHow much water the sieve holds at equilibrium under the stated conditionsWorking capacity at your conditions — always lower than the equilibrium figure
Bulk densityWhat the bed weighs, so what the vessel has to carryAnything about performance
Crushing strengthWhether the beads survive loading and pressure cyclingResistance to attrition in motion — that is a separate test
AttritionHow much dust is generated in handling and cyclingWhat happens after thousands of regenerations
Loss on ignitionHow much water and volatile material is still in the poresWhether the sieve was packed dry — check moisture as packed as well
Size rangePressure drop and how evenly the bed packsWhether fines were removed — ask about de-dusting

Equilibrium capacity is measured under laboratory conditions. Working capacity in a real bed is set by the regeneration temperature, the cycle time and how completely the bed is regenerated — it is always lower, and that is the number the design should use.

Regeneration

Thermal swing

Typically 200–300 °C for molecular sieve; confirm the window for your grade. A dry purge gas at 0.3–0.5 kg/cm2 for 3–4 hours, with the outlet reaching 110–180 °C, then cool.

What damages a bed

Regenerating too hot, regenerating with a wet purge gas, and cooling with gas that still carries water — all three leave capacity on the table permanently.

Organic fouling

Heavy organics coke in the pores. Strip with steam before the thermal step, or the bed loses capacity that no amount of heating brings back.

Pressure swing

No heat: the bed is regenerated by depressurisation and a purge. This is how PSA nitrogen and VPSA oxygen plants run, and why cycle time is a design variable.

When to replace

When working capacity no longer reaches the outlet specification within the cycle, or when pressure drop rises from fines — not on a fixed calendar.

Storage

Keep sealed, off the floor, out of humid air. Activated sieve picks up moisture within hours once the liner is opened.

Send us the duty

We will work it through with you

Stream composition, pressure, temperature, flow, target outlet, cycle time and regeneration method are enough for us to recommend a grade, size the bed and quote. If a vessel already exists, send the drawing and we will check whether an existing grade can be matched.

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In this section

Table mapping common industrial applications to the recommended molecular sieve grade, from insulating glass 3A to carbon molecular sieve for nitrogen generation
Table mapping common industrial applications to the recommended molecular sieve grade, from insulating glass 3A to carbon molecular sieve for nitrogen generation
Chart of molecular sieve breakthrough showing outlet moisture rising as the adsorption zone reaches the end of the bed, with the switch point marked
Chart of molecular sieve breakthrough showing outlet moisture rising as the adsorption zone reaches the end of the bed, with the switch point marked
Bar chart comparing 3A, 4A, 5A and 13X molecular sieve pore openings with the kinetic diameter of water, CO2, nitrogen and other common molecules
Bar chart comparing 3A, 4A, 5A and 13X molecular sieve pore openings with the kinetic diameter of water, CO2, nitrogen and other common molecules

Selection help, free of charge

Email sales@zeolitemolecularsieve.com — a recommendation costs you nothing whether or not you buy from us.

Market and buying guides

Published price indicators, cost structure, demand trends and import practice — written for buyers specifying molecular sieve.

Decision guides for specifying a bed

How to choose between desiccants, pick a bead size, classify the goods for customs, diagnose an underperforming bed, and spec a biogas train.

Process and operations guides

Ethanol dehydration, nitrogen generation, bed sizing, regeneration practice and warehouse handling.

Product-duty guides

Oxygen generation, gas dehydration, insulating glass, air pre-purification and compressed-air drying – grade selection for each duty.

Bulk supply and procurement guides

Order mechanics for industrial buyers: minimum quantities, packing, FCA and EXW terms, the document pack, and replacement planning for PSA nitrogen generators.